Non-thermal plasma-based nitrogen fixation

This innovation uses non-thermal plasma technology to ionize atmospheric nitrogen and oxygen, forming reactive species that are absorbed into water, enriching it with plant-available nitrates and nitrites for sustainable fertilization.

closeup of plasma

Priorities for scaling

high-risk pilotingcatalysing development

This innovation leverages non-thermal plasma technology to ionize atmospheric nitrogen and oxygen, forming reactive species that are absorbed into water, enriching it with plant-available nitrates and nitrites (e.g. nitric acid).

Plasma is the fourth state of matter, and can be artificially generated from subjecting a neutral gas to a strong electric field. Lighting, for example, is a common and naturally occurring generator of plasma. Non-thermal plasma refers to partially ionised plasma, meaning that only the electron temperature is highly elevated, while the rest of the gas, ions and neutral atoms, stay around room temperature. As such, nitrogen fixation through non-thermal plasma application is a form of biomimicry; in nature, lighting strikes water with such energy that it breaks apart atmospheric nitrogen molecules, allowing them to ionise with atmospheric oxygen, forming reactive oxygen and nitrogen species (RONS). Resulting nitrates and nitrites are then absorbed into water, ready to be applied to the field for fertilisation.

Current technologies in this field replicate this process industrially through, for example, discharging lightning into water in the presence of air to produce such ‘nitrogen-enriched’ or ‘plasma-activated’ water. Different types of non-thermal plasma technologies can be applied in different ways (e.g. ionic gas bubbled through water versus also ionizing water molecules) to manipulate the properties and concentrations of the resulting enriched water.

Thus, with only air, water and renewable electricity, atmospheric nitrogen can be fixed into aqueous plant-available nitrogen (low-concentration nitric acid) for fertilisation. It operates without the need for high pressures, extreme temperatures, nor any finite resources, making it a low-emission, energy-efficient and fossil-fuel free alternative to the Haber-Bosch process for nitrogen fertiliser production.

Food System Area

agricultural inputs & primary production practiceswaste

The overarching problem addressed is the environmental footprint of conventional nitrogen fertiliser production, dominated by the fossil-fuel reliant, energy-intensive and highly polluting Haber-Bosch process. By providing a clean alternative run on renewable electricity, reliant only on air and water as additional inputs, non-thermal plasma-based nitrogen fixation aims to mitigate the environmental impact of current fertiliser production through offering an alternative, potentially net-zero, solution. It additionally allows for more decentralised and on-site production, reducing transportation emissions and enabling more equitable fertiliser accessibility.

Problem area

reducing agricultural footprint

What impact could it have?

What factors influence scaling?

This innovation needs to be integrated with renewable energy generation to supply electricity. Additionally, potential integration with irrigation systems should be considered.

This innovation is applicable to globall geographic contexts, particularly for soils that work well with nitrate fertilizers. It’s particularly suited to decentralized and smaller-scale contexts.

Due to ongoing development, small-scale food system actors with enough financial resources will be likely to take up this innovation first, e.g. orchards. It is very well suited for decentralisation, but start-up costs currently pose a barrier for uptake in resource-poor areas. Some sort of irrigation system is highly beneficial for application.

The potential for disruption is medium to high, particularly concerning existing synthetic fertiliser production systems and associated value chains.

NTP Technologies Plasma 2X Limited Nitricity PlasmaLeaps VitalFluid Plasma Solutions NitroCapt

Unless the plants come with an integrated energy system, a significant increase in energy demand to scale the innovation could strain renewable energy grids. This could potentially divert energy from other critical use or change commodity prices. Unintended environmental impacts associated with the production and sourcing of renewable energy are possible.
Lightning strike hitting water surface at night illustrating non thermal plasma nitrogen fixation

Where is acceleration most needed?

Accelerator scores reflect the degree of action needed across eight key accelerators of change that can enable an innovation to scale. A higher score signals that greater effort and support are needed in that area to unlock uptake at scale. Click on each accelerator to see what’s been achieved and what still needs attention.

Building Trust

Medium level
Medium

Building Trust

Building trust amongst actors in the food system is important for such on-site modular designs, as primary producers may integrate with the fertiliser production industry. The proposed changes furthermore primarily affect fossil fuel industries and current production value chains, aligning with global efforts to shift away from them, potentially necessitating regulatory framework adjustments.

Transforming Mindsets

Low level
Low

Transforming Mindsets

This innovation tackles the production of synthetic fertilisers, primarily affecting fossil fuel companies and traditional producers. It falls in line with a global shift to greener technologies and does not introduce a new or novel product; rather a new way of producing the same output.

Enabling Social License

High level
High

Enabling Social License

Gaining social licence is crucial to drive research and development efforts forward, especially as much development is required before achieving commercial viability.

Ensuring Stable Finance

High level
High

Ensuring Stable Finance

Securing stable financing is essential to support research and development efforts aimed at optimising the nitrogen fixation process and achieving commercial viability.

Designing Market Incentives

Medium level
Medium

Designing Market Incentives

As this innovation is not producing a new output, there is already a healthy market present. However, financial incentives remain essential to spread risks. This technology is still very new and immature, requiring further development.

Changing Policies and Regulations

High level
High

Changing Policies and Regulations

With any new and novel type of technology come potential changes and expansions in policy and regulations. Decentralised production poses potential safety and security risks, necessitating regulatory monitoring and potential adjustments.

Safeguarding Against Undesirable Effects

High level
High

Safeguarding Against Undesirable Effects

Non-thermal plasma remains relatively new in agricultural application, requiring consistent monitoring and evaluation to safeguard from undesirable effects. Economic viability remains of paramount importance, necessitating continuous market monitoring.

Developing Transition Pathways

Medium level
Medium

Developing Transition Pathways

Non-thermal plasma-based nitrogen fixation provides a complete alternative production process to conventional Haber-Bosch production, representing a new generation of technologies. Preparation of infrastructure and an enabling policy and regulatory environment is crucial for a smooth transitional. A widespread renewable grid is also of utmost importance for industrial-scale facilities.

Reference

Borkar, S. B., Negi, M., Kaushik, N., Abdul Munnaf, S., Nguyen, L. N., Choi, E. H., & Kaushik, N. K. (2023). Plasma-generated nitric oxide water mediates environmentally transmitted pathogenic bacterial inactivation via intracellular nitrosative stress. International Journal of Molecular Sciences, 24(3), 1901. https://doi.org/10.3390/ijms24031901

 

Davide. (2024, June 16). Applications of Plasma Activated Water (PAW). SCIPlasma. https://www.sciplasma.com/post/plasma-activated-water

 

Guo, D., Liu, H., Zhou, L., Xie, J., & He, C. (2021). Plasma-activated water production and its application in agriculture. Journal of the Science of Food and Agriculture, 101(12), 4891–4899. https://doi.org/10.1002/jsfa.11258

 

Pakprom, J., Santalunai, S., Charoensiri, W., Ramjanthuk, S., Janpangngern, P., Thongsopa, C., Thosdeekoraphat, T., Santalunai, N., & Santalunai, S. (2024). Optimizing Nitrate Fertilizer Production Using Plasma-Activated Water (PAW) Technology: An Analysis of Dielectric Properties. Applied Sciences, 14(21), 9997. https://doi.org/10.3390/app14219997

 

Plasma activated water. VitalFluid. https://vitalfluid.com/plasma-activated-water/

 

Plasma Processing of Water and Inedible Biomass for pH Control and Nutrient Recycling (KSC-TOPS-94). NASA Technology Transfer Program. https://technology.nasa.gov/patent/KSC-TOPS-94

 

Punith, N., Harsha, R., Lakshminarayana, R., Hemanth, M., Anand, M. S., & Dasappa, S. (2019). Plasma-activated water generation and its application in agriculture. Advanced Materials Letters, 10, 700–704. https://doi.org/10.5185/amlett.2019.0042

 

Sze, C., Wang, B., Xu, J., Rivas-Davila, J., & Cappelli, M. A. (2021). Plasma-fixated nitrogen as fertilizer for turf grass. RSC Advances, 11(60), 37886–37895. https://doi.org/10.1039/d1ra07074f

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